Download e-book for iPad: Carbohydrate Chemistry Volume 8 by C. S. And Wolfrom, M. L. (editors) Hudson

By C. S. And Wolfrom, M. L. (editors) Hudson

ISBN-10: 0851860729

ISBN-13: 9780851860725

ISBN-10: 1847552854

ISBN-13: 9781847552853

This product isn't really to be had individually, it's only offered as a part of a suite. There are 750 items within the set and those are all offered as one entity. summary: This product isn't on hand individually, it's only offered as a part of a suite. There are 750 items within the set and those are all bought as one entity

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1974, 34, 208. P. A. Gent and R. S. Perkin I , 1974, 1446. J. Schneider, Y . C. Lee, and H. M. , 1974, 36, 159. J. C. -M. Petit, and P. , 1974, 38, 305. P. A. Gent and R. S. Chem. , 1974,277. 171 Condensation of (52) with benzyl 2,3,4-tri-0-benzyl-o-~galactopyranoside yielded the a-linked disaccharide derivative; the but-2-enyl group could then be removed selectively (KOBut-DMSO) to give a product suitable for the synthesis of trisaccharides. All six tritylmaltose peracetates (6a, 6/3, 6’a, 6’p, 6,6’a, and 6,6’15) have been isolated following tritylation of maltose and subsequent a ~ e t y 1 a t i o n .

In the D-galactose series, the 3,6-di-O-methyl ether has been obtained by opening of a terminal epoxide, 15' and syntheses of 3,4-di- and 3,4,6-tri-O-methyl-~m a n n o p y r a n ~ s e ,and ~ ~ ~6-mono- and 3,6- and 4,6-di-O-methyl ethers of methyl 2-acetamido-2-deoxy-a-~-mannopyranoside have been 160 and 3- and 4-mono- and In the deoxyhexose series, 2,3-di-O-methyl-~-fucose 161have been prepared ; 3,4-di-O-methyl ethers of 2-amino-2,6-dideoxy-~-glucose the dimethylated derivative was obtained from 3,4-di-O-methyl-~-rharnnal by way of the addition of nitrosyl chloride, which also provided access to the 4-0-methyl ether.

S. Perkin I, 1974, 388. S. A. S. A1 Janabi, J. G. Buchanan, and A. R. , 1974,35, 151. R. D. Guthrie and J. A. , 1974, 33, 355. S. Kumazawa, T. Sakakibara, R. Sudoh, and T. Nakagawa, Angew. Chem. Znternat. , 1973,12,921. 34 Carbohydrate Chemistry (61) R = Me or Ph Scheme 20 (62) X = Br (63) X = N3 (65) X = Br or N3 (64) Studies directed at the synthesis of hexosides from unresolved 2-alkoxydihydropyrans and 3,4-anhydrides derived therefrom have been reported,ls3 and the compound (66), obtained from L-glutamic acid (see Vol.

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Carbohydrate Chemistry Volume 8 by C. S. And Wolfrom, M. L. (editors) Hudson


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